Magnetic properties of the lanthanoid nickel arsenides and phosphides LnNi4X2 with ZrFe4Si2-type structure
Identifieur interne : 000368 ( France/Analysis ); précédent : 000367; suivant : 000369Magnetic properties of the lanthanoid nickel arsenides and phosphides LnNi4X2 with ZrFe4Si2-type structure
Auteurs : S. Députier [France] ; O. Pe A [France] ; T. Le Bihan [France] ; J. Y. Pivan [France] ; R. Guérin [France]Source :
- Physica B: Physics of Condensed Matter [ 0921-4526 ] ; 1997.
Abstract
The ternary compounds LnNi4As2 (Ln: Tb → Yb; Y) and LnNi4P2 (Ln:Er, Yb; Y) have been prepared; they crystallize in the tetragonal ZrFe4Si2-type structure. Their magnetic properties have been studied with a SQUID magnetometer between 2 and 300 K. YNi4As2 shows a temperature-independent Pauli paramagnetism attributed to a non-magnetic contribution of the “Ni4As2” sublattice, while all the other LnNi4As2 compounds, except YbNi4As2, present a Curie-Weiss behavior above 30 K. The experimental paramagnetic moments are close to those expected for Ln3+ -free ions. At low temperature, only two compounds exhibit a magnetic ordering: TbNi4As2 behaves as a metamagnetic or spin-canted system, while DyNi4As2 is a weak ferromagnet. At last, YbNi4As2 shows a temperature-independent paramagnetism suggesting that ytterbium is in a non-magnetic divalent state. For the phosphides LnNi4P2 (Ln: Er, Yb, Y), a non-magnetic contribution of the “Ni4P2” sublattice is found, as shown by the study of YNi4P2. ErNi4P2 exhibits a Curie-Weiss paramagnetism in the whole temperature range as well as YbNi4P2 for T > 20 K. This last result shows that contrary to YbNi4As2, the corresponding phosphide exhibits a trivalent state for ytterbium.
Url:
DOI: 10.1016/S0921-4526(97)00004-5
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 001461
- to stream Istex, to step Curation: 000F46
- to stream Istex, to step Checkpoint: 000775
- to stream Main, to step Merge: 000F63
- to stream Main, to step Curation: 000F25
- to stream Main, to step Exploration: 000F25
- to stream France, to step Extraction: 000368
Links to Exploration step
ISTEX:D3D8F6D6545AA00F5382807ABD0E892659A40E6FLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Magnetic properties of the lanthanoid nickel arsenides and phosphides LnNi4X2 with ZrFe4Si2-type structure</title><author><name sortKey="Deputier, S" sort="Deputier, S" uniqKey="Deputier S" first="S." last="Députier">S. Députier</name></author><author><name sortKey="Pe A, O" sort="Pe A, O" uniqKey="Pe A O" first="O." last="Pe A">O. Pe A</name></author><author><name sortKey="Le Bihan, T" sort="Le Bihan, T" uniqKey="Le Bihan T" first="T." last="Le Bihan">T. Le Bihan</name></author><author><name sortKey="Pivan, J Y" sort="Pivan, J Y" uniqKey="Pivan J" first="J. Y." last="Pivan">J. Y. Pivan</name></author><author><name sortKey="Guerin, R" sort="Guerin, R" uniqKey="Guerin R" first="R." last="Guérin">R. Guérin</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:D3D8F6D6545AA00F5382807ABD0E892659A40E6F</idno><date when="1997" year="1997">1997</date><idno type="doi">10.1016/S0921-4526(97)00004-5</idno><idno type="url">https://api.istex.fr/document/D3D8F6D6545AA00F5382807ABD0E892659A40E6F/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001461</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001461</idno><idno type="wicri:Area/Istex/Curation">000F46</idno><idno type="wicri:Area/Istex/Checkpoint">000775</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000775</idno><idno type="wicri:doubleKey">0921-4526:1997:Deputier S:magnetic:properties:of</idno><idno type="wicri:Area/Main/Merge">000F63</idno><idno type="wicri:Area/Main/Curation">000F25</idno><idno type="wicri:Area/Main/Exploration">000F25</idno><idno type="wicri:Area/France/Extraction">000368</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Magnetic properties of the lanthanoid nickel arsenides and phosphides LnNi4X2 with ZrFe4Si2-type structure</title><author><name sortKey="Deputier, S" sort="Deputier, S" uniqKey="Deputier S" first="S." last="Députier">S. Députier</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 66511, Université de Rennes I, Avenue de Général Leclerc, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName><orgName type="university">Université de Rennes 1</orgName></affiliation></author><author><name sortKey="Pe A, O" sort="Pe A, O" uniqKey="Pe A O" first="O." last="Pe A">O. Pe A</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 66511, Université de Rennes I, Avenue de Général Leclerc, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName><orgName type="university">Université de Rennes 1</orgName></affiliation></author><author><name sortKey="Le Bihan, T" sort="Le Bihan, T" uniqKey="Le Bihan T" first="T." last="Le Bihan">T. Le Bihan</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 66511, Université de Rennes I, Avenue de Général Leclerc, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName><orgName type="university">Université de Rennes 1</orgName></affiliation></author><author><name sortKey="Pivan, J Y" sort="Pivan, J Y" uniqKey="Pivan J" first="J. Y." last="Pivan">J. Y. Pivan</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 66511, Université de Rennes I, Avenue de Général Leclerc, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName><orgName type="university">Université de Rennes 1</orgName></affiliation></author><author><name sortKey="Guerin, R" sort="Guerin, R" uniqKey="Guerin R" first="R." last="Guérin">R. Guérin</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 66511, Université de Rennes I, Avenue de Général Leclerc, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName><orgName type="university">Université de Rennes 1</orgName></affiliation></author></analytic><monogr></monogr><series><title level="j">Physica B: Physics of Condensed Matter</title><title level="j" type="abbrev">PHYSB</title><idno type="ISSN">0921-4526</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997">1997</date><biblScope unit="volume">233</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="26">26</biblScope><biblScope unit="page" to="36">36</biblScope></imprint><idno type="ISSN">0921-4526</idno></series><idno type="istex">D3D8F6D6545AA00F5382807ABD0E892659A40E6F</idno><idno type="DOI">10.1016/S0921-4526(97)00004-5</idno><idno type="PII">S0921-4526(97)00004-5</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0921-4526</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The ternary compounds LnNi4As2 (Ln: Tb → Yb; Y) and LnNi4P2 (Ln:Er, Yb; Y) have been prepared; they crystallize in the tetragonal ZrFe4Si2-type structure. Their magnetic properties have been studied with a SQUID magnetometer between 2 and 300 K. YNi4As2 shows a temperature-independent Pauli paramagnetism attributed to a non-magnetic contribution of the “Ni4As2” sublattice, while all the other LnNi4As2 compounds, except YbNi4As2, present a Curie-Weiss behavior above 30 K. The experimental paramagnetic moments are close to those expected for Ln3+ -free ions. At low temperature, only two compounds exhibit a magnetic ordering: TbNi4As2 behaves as a metamagnetic or spin-canted system, while DyNi4As2 is a weak ferromagnet. At last, YbNi4As2 shows a temperature-independent paramagnetism suggesting that ytterbium is in a non-magnetic divalent state. For the phosphides LnNi4P2 (Ln: Er, Yb, Y), a non-magnetic contribution of the “Ni4P2” sublattice is found, as shown by the study of YNi4P2. ErNi4P2 exhibits a Curie-Weiss paramagnetism in the whole temperature range as well as YbNi4P2 for T > 20 K. This last result shows that contrary to YbNi4As2, the corresponding phosphide exhibits a trivalent state for ytterbium.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Région Bretagne</li></region><settlement><li>Rennes</li></settlement><orgName><li>Université de Rennes 1</li></orgName></list><tree><country name="France"><region name="Région Bretagne"><name sortKey="Deputier, S" sort="Deputier, S" uniqKey="Deputier S" first="S." last="Députier">S. Députier</name></region><name sortKey="Guerin, R" sort="Guerin, R" uniqKey="Guerin R" first="R." last="Guérin">R. Guérin</name><name sortKey="Le Bihan, T" sort="Le Bihan, T" uniqKey="Le Bihan T" first="T." last="Le Bihan">T. Le Bihan</name><name sortKey="Pe A, O" sort="Pe A, O" uniqKey="Pe A O" first="O." last="Pe A">O. Pe A</name><name sortKey="Pivan, J Y" sort="Pivan, J Y" uniqKey="Pivan J" first="J. Y." last="Pivan">J. Y. Pivan</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/France/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000368 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000368 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= CobaltMaghrebV1
|flux= France
|étape= Analysis
|type= RBID
|clé= ISTEX:D3D8F6D6545AA00F5382807ABD0E892659A40E6F
|texte= Magnetic properties of the lanthanoid nickel arsenides and phosphides LnNi4X2 with ZrFe4Si2-type structure
}}
| This area was generated with Dilib version V0.6.32. |  |